Appendix C: Additional Figures and Tables

Figure C.1: Supplement to Chapter 2: Simulated concentration of methane at the injection/extraction well and at the 50 m well.

Figure C.2: Supplement to Chapter 2: Simulated concentration profile of Bacteria at 100, 530 and 780 days after the start of the trial.

Figure C.3: Supplement to Chapter 2: Simulated and observed concentration of calcium at the injection/extrac tion well and at the 50 m well. The comparison of simulations with and without biodegradation indicates that biodegradation of organic carbon only had a minor impact on calcite dissolution.

Figure C.4: Supplement to Chapter 2: Simulated and observed concentration of Fe (ferric+ferrous) at the injection/extraction well and at the 50 m well. Simulation with and without FeS precipitation allowed.

Figure C.5: Supplement to Chapter 2: Simulated and observed concentration of sulfate and Fe (ferric+ferrous) at the 4m well.

Figure C.6: Supplement to Chapter 3: Pressures at depths of 50 cm and 150 cm below the pond; the numbers 1-4 refer to the Stages 1-4 of the operational cycle. Note that the pond was dry during Stage 4.

Table C.1: Supplement to Chapter 2: Parameter correlation coefficient matrix.

rattach

Csat

β

vdecay_Aerobes/Denitr

vdecay_Iron/Sulf. reducers

rox

rnitr

Xmax

rhem/sulf

Kinh_ox

rFeS

Kox

Knitr

Ksulfate

Khematite

KNH4+

KDOC

rattach

1.00

-0.11

0.17

-0.05

0.07

-0.18

0.28

0.18

0.24

0.47

-0.09

0.03

-0.38

0.00

-0.05

0.17

0.36

Csat

-0.11

1.00

-0.09

0.07

0.06

0.14

-0.09

-0.08

0.02

-0.12

-0.05

0.01

0.15

-0.08

0.21

0.03

-0.35

β

0.17

-0.09

1.00

0.07

-0.10

0.20

0.13

-0.03

-0.07

0.19

-0.04

0.10

-0.24

-0.13

0.05

0.06

0.45

vdecay_Aerobes/Denitr

-0.05

0.07

0.07

1.00

-0.35

0.15

0.33

-0.69

-0.28

-0.06

0.14

0.02

-0.04

-0.37

-0.22

0.16

0.07

vdecay_Iron/Sulf. reducers

0.07

0.06

-0.10

-0.35

1.00

0.05

-0.14

0.09

0.60

0.01

0.09

0.20

-0.08

0.01

0.22

-0.43

-0.25

rox

-0.18

0.14

0.20

0.15

0.05

1.00

-0.12

-0.05

0.21

0.00

0.24

0.24

0.02

-0.22

0.20

0.28

-0.06

rnitr

0.28

-0.09

0.13

0.33

-0.14

-0.12

1.00

0.01

0.09

-0.07

-0.04

0.01

-0.39

-0.11

-0.09

0.33

0.29

Xmax

0.18

-0.08

-0.03

-0.69

0.09

-0.05

0.01

1.00

0.24

0.07

-0.04

-0.02

-0.14

0.22

0.17

0.18

0.04

rhem/sulf

0.24

0.02

-0.07

-0.28

0.60

0.21

0.09

0.24

1.00

0.03

0.02

0.02

-0.29

0.05

0.23

0.29

-0.02

Kinh_ox

0.47

-0.12

0.19

-0.06

0.01

0.00

-0.07

0.07

0.03

1.00

-0.04

0.12

0.15

-0.01

-0.39

-0.05

0.41

rFeS

-0.09

-0.05

-0.04

0.14

0.09

0.24

-0.04

-0.04

0.02

-0.04

1.00

0.09

0.19

-0.18

0.13

0.01

-0.33

Kox

0.03

0.01

0.10

0.02

0.20

0.24

0.01

-0.02

0.02

0.12

0.09

1.00

-0.06

-0.05

-0.02

-0.19

-0.04

Knitr

-0.38

0.15

-0.24

-0.04

-0.08

0.02

-0.39

-0.14

-0.29

0.15

0.19

-0.06

1.00

0.04

0.06

-0.33

-0.32

Ksulfate

0.00

-0.08

-0.13

-0.37

0.01

-0.22

-0.11

0.22

0.05

-0.01

-0.18

-0.05

0.04

1.00

0.15

-0.17

0.07

Khematite

-0.05

0.21

0.05

-0.22

0.22

0.20

-0.09

0.17

0.23

-0.39

0.13

-0.02

0.06

0.15

1.00

0.00

-0.32

KNH4+

0.17

0.03

0.06

0.16

-0.43

0.28

0.33

0.18

0.29

-0.05

0.01

-0.19

-0.33

-0.17

0.00

1.00

0.09

KDOC

0.36

-0.35

0.45

0.07

-0.25

-0.06

0.29

0.04

-0.02

0.41

-0.33

-0.04

-0.32

0.07

-0.32

0.09

1.00

Table C.2: Supplement to Chapter 2: Confidence intervals for the estimated parameter values.

Parameter

95% percent confidence limits

Lower limit

Upper limit

rattach

8.19

15.5

Csat

4.06 x 10-03

5.24 x 10-03

β

2.39 x 10-03

6.87 x 10-03

vdecay_Aerobes/Denitr

8.98 x 10-03

1.16 x 10-02

vdecay_Iron/Sulf. reducers

8.68 x 10-03

1.31 x 10-02

rox

8.96

10.4

rnitr

4.95

5.77

Xmax

6.27 x 10-01

7.33 x 10-01

rhem/sulf

4.35 x 10-01

5.05 x 10-01

Kinh_ox

7.38 x 10-06

1.26 x 10-05

rFeS

4.56 x 10-07

5.80 x 10-07

Kox

6.25 x 10-05

1.17 x 10-04

Knitr

1.01 x 10-04

1.39 x 10-04

Ksulfate

2.97 x 10-05

1.76 x 10-04

Khematite

-6.04 x 10-05

4.40 x 10-04

KNH4+

3.68 x 10-05

1.83 x 10-04

KDOC

1.22 x 10-04

1.66 x 10-04


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