| Figure C.1: Supplement to Chapter 2: Simulated concentration of methane at the injection/extraction well and at the 50 m well. | ||
|
|
| Figure C.2: Supplement to Chapter 2: Simulated concentration profile of Bacteria at 100, 530 and 780 days after the start of the trial. | ||
|
|
| Figure C.3: Supplement to Chapter 2: Simulated and observed concentration of calcium at the injection/extrac tion well and at the 50 m well. The comparison of simulations with and without biodegradation indicates that biodegradation of organic carbon only had a minor impact on calcite dissolution. | ||
|
|
| Figure C.4: Supplement to Chapter 2: Simulated and observed concentration of Fe (ferric+ferrous) at the injection/extraction well and at the 50 m well. Simulation with and without FeS precipitation allowed. | ||
|
|
| Figure C.5: Supplement to Chapter 2: Simulated and observed concentration of sulfate and Fe (ferric+ferrous) at the 4m well. | ||
|
|
| Figure C.6: Supplement to Chapter 3: Pressures at depths of 50 cm and 150 cm below the pond; the numbers 1-4 refer to the Stages 1-4 of the operational cycle. Note that the pond was dry during Stage 4. | ||
|
|
Table C.1: Supplement to Chapter 2: Parameter correlation coefficient matrix.
|
rattach |
Csat |
β |
vdecay_Aerobes/Denitr |
vdecay_Iron/Sulf. reducers |
rox |
rnitr |
Xmax |
rhem/sulf |
Kinh_ox |
rFeS |
Kox |
Knitr |
Ksulfate |
Khematite |
KNH4+ |
KDOC |
|
|
rattach |
1.00 |
-0.11 |
0.17 |
-0.05 |
0.07 |
-0.18 |
0.28 |
0.18 |
0.24 |
0.47 |
-0.09 |
0.03 |
-0.38 |
0.00 |
-0.05 |
0.17 |
0.36 |
|
Csat |
-0.11 |
1.00 |
-0.09 |
0.07 |
0.06 |
0.14 |
-0.09 |
-0.08 |
0.02 |
-0.12 |
-0.05 |
0.01 |
0.15 |
-0.08 |
0.21 |
0.03 |
-0.35 |
|
β |
0.17 |
-0.09 |
1.00 |
0.07 |
-0.10 |
0.20 |
0.13 |
-0.03 |
-0.07 |
0.19 |
-0.04 |
0.10 |
-0.24 |
-0.13 |
0.05 |
0.06 |
0.45 |
|
vdecay_Aerobes/Denitr |
-0.05 |
0.07 |
0.07 |
1.00 |
-0.35 |
0.15 |
0.33 |
-0.69 |
-0.28 |
-0.06 |
0.14 |
0.02 |
-0.04 |
-0.37 |
-0.22 |
0.16 |
0.07 |
|
vdecay_Iron/Sulf. reducers |
0.07 |
0.06 |
-0.10 |
-0.35 |
1.00 |
0.05 |
-0.14 |
0.09 |
0.60 |
0.01 |
0.09 |
0.20 |
-0.08 |
0.01 |
0.22 |
-0.43 |
-0.25 |
|
rox |
-0.18 |
0.14 |
0.20 |
0.15 |
0.05 |
1.00 |
-0.12 |
-0.05 |
0.21 |
0.00 |
0.24 |
0.24 |
0.02 |
-0.22 |
0.20 |
0.28 |
-0.06 |
|
rnitr |
0.28 |
-0.09 |
0.13 |
0.33 |
-0.14 |
-0.12 |
1.00 |
0.01 |
0.09 |
-0.07 |
-0.04 |
0.01 |
-0.39 |
-0.11 |
-0.09 |
0.33 |
0.29 |
|
Xmax |
0.18 |
-0.08 |
-0.03 |
-0.69 |
0.09 |
-0.05 |
0.01 |
1.00 |
0.24 |
0.07 |
-0.04 |
-0.02 |
-0.14 |
0.22 |
0.17 |
0.18 |
0.04 |
|
rhem/sulf |
0.24 |
0.02 |
-0.07 |
-0.28 |
0.60 |
0.21 |
0.09 |
0.24 |
1.00 |
0.03 |
0.02 |
0.02 |
-0.29 |
0.05 |
0.23 |
0.29 |
-0.02 |
|
Kinh_ox |
0.47 |
-0.12 |
0.19 |
-0.06 |
0.01 |
0.00 |
-0.07 |
0.07 |
0.03 |
1.00 |
-0.04 |
0.12 |
0.15 |
-0.01 |
-0.39 |
-0.05 |
0.41 |
|
rFeS |
-0.09 |
-0.05 |
-0.04 |
0.14 |
0.09 |
0.24 |
-0.04 |
-0.04 |
0.02 |
-0.04 |
1.00 |
0.09 |
0.19 |
-0.18 |
0.13 |
0.01 |
-0.33 |
|
Kox |
0.03 |
0.01 |
0.10 |
0.02 |
0.20 |
0.24 |
0.01 |
-0.02 |
0.02 |
0.12 |
0.09 |
1.00 |
-0.06 |
-0.05 |
-0.02 |
-0.19 |
-0.04 |
|
Knitr |
-0.38 |
0.15 |
-0.24 |
-0.04 |
-0.08 |
0.02 |
-0.39 |
-0.14 |
-0.29 |
0.15 |
0.19 |
-0.06 |
1.00 |
0.04 |
0.06 |
-0.33 |
-0.32 |
|
Ksulfate |
0.00 |
-0.08 |
-0.13 |
-0.37 |
0.01 |
-0.22 |
-0.11 |
0.22 |
0.05 |
-0.01 |
-0.18 |
-0.05 |
0.04 |
1.00 |
0.15 |
-0.17 |
0.07 |
|
Khematite |
-0.05 |
0.21 |
0.05 |
-0.22 |
0.22 |
0.20 |
-0.09 |
0.17 |
0.23 |
-0.39 |
0.13 |
-0.02 |
0.06 |
0.15 |
1.00 |
0.00 |
-0.32 |
|
KNH4+ |
0.17 |
0.03 |
0.06 |
0.16 |
-0.43 |
0.28 |
0.33 |
0.18 |
0.29 |
-0.05 |
0.01 |
-0.19 |
-0.33 |
-0.17 |
0.00 |
1.00 |
0.09 |
|
KDOC |
0.36 |
-0.35 |
0.45 |
0.07 |
-0.25 |
-0.06 |
0.29 |
0.04 |
-0.02 |
0.41 |
-0.33 |
-0.04 |
-0.32 |
0.07 |
-0.32 |
0.09 |
1.00 |
Table C.2: Supplement to Chapter 2: Confidence intervals for the estimated parameter values.
|
Parameter |
95% percent confidence limits |
|
|
Lower limit |
Upper limit |
|
|
rattach |
8.19 |
15.5 |
|
Csat |
4.06 x 10-03 |
5.24 x 10-03 |
|
β |
2.39 x 10-03 |
6.87 x 10-03 |
|
vdecay_Aerobes/Denitr |
8.98 x 10-03 |
1.16 x 10-02 |
|
vdecay_Iron/Sulf. reducers |
8.68 x 10-03 |
1.31 x 10-02 |
|
rox |
8.96 |
10.4 |
|
rnitr |
4.95 |
5.77 |
|
Xmax |
6.27 x 10-01 |
7.33 x 10-01 |
|
rhem/sulf |
4.35 x 10-01 |
5.05 x 10-01 |
|
Kinh_ox |
7.38 x 10-06 |
1.26 x 10-05 |
|
rFeS |
4.56 x 10-07 |
5.80 x 10-07 |
|
Kox |
6.25 x 10-05 |
1.17 x 10-04 |
|
Knitr |
1.01 x 10-04 |
1.39 x 10-04 |
|
Ksulfate |
2.97 x 10-05 |
1.76 x 10-04 |
|
Khematite |
-6.04 x 10-05 |
4.40 x 10-04 |
|
KNH4+ |
3.68 x 10-05 |
1.83 x 10-04 |
|
KDOC |
1.22 x 10-04 |
1.66 x 10-04 |
| © Die inhaltliche Zusammenstellung und Aufmachung dieser Publikation sowie die elektronische Verarbeitung sind urheberrechtlich geschützt. Jede Verwertung, die nicht ausdrücklich vom Urheberrechtsgesetz zugelassen ist, bedarf der vorherigen Zustimmung. Das gilt insbesondere für die Vervielfältigung, die Bearbeitung und Einspeicherung und Verarbeitung in elektronische Systeme. | ||
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