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[page 125↓]List of Symbols
|
Ru |
resistance of the solution phase or the polymer/solution phase in Ω |
|
Cdl |
double layer capacitance at the electrode/solution or electrode/polymer interface in F (farads) |
|
kex |
rate constant for the electrochemiluminescence (ECL) reaction l mol-1s-1 |
|
D |
diffusion coefficient in cm2s-1 |
|
Dap |
apparent diffusion coefficient in cm2s-1 |
|
Dap f |
apparent diffusion coefficient in the first potential step in cm2s-1 |
|
DM |
dimension less diffusion coefficient used in the simulation |
|
l |
diffusion layer thickness in cm |
|
Δx |
increment of distance in the simulation procedure |
|
t |
time in s (seconds) |
|
Δt |
increment of time in the simulation procedure |
|
tw |
waiting period in s |
|
E |
potential in V (volts) |
|
ν |
scan rate in Vs-1 |
|
IF |
Faradaic current in A (amperes) |
|
Idl |
Charging current in A (amperes). |
|
j |
current density in Acm-2 |
|
C |
concentration in molcm-3 |
|
J |
flux of species in mol cm-2 s-1 |
|
R |
gas constant JK-1mol-1 |
|
B |
strength of magnetic field in kilo Gauss |
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