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[page 125↓]List of Symbols

Ru

resistance of the solution phase or the polymer/solution phase in Ω

Cdl

double layer capacitance at the electrode/solution or electrode/polymer interface in F (farads)

kex

rate constant for the electrochemiluminescence (ECL) reaction l mol-1s-1

D

diffusion coefficient in cm2s-1

Dap

apparent diffusion coefficient in cm2s-1

Dap f

apparent diffusion coefficient in the first potential step in cm2s-1

DM

dimension less diffusion coefficient used in the simulation

l

diffusion layer thickness in cm

Δx

increment of distance in the simulation procedure

t

time in s (seconds)

Δt

increment of time in the simulation procedure

tw

waiting period in s

E

potential in V (volts)

ν

scan rate in Vs-1

IF

Faradaic current in A (amperes)

Idl

Charging current in A (amperes).

j

current density in Acm-2

C

concentration in molcm-3

J

flux of species in mol cm-2 s-1

R

gas constant JK-1mol-1

B

strength of magnetic field in kilo Gauss


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