| Prescott, Hillary A.: The Crystal Structures and Thermal Behavior of Hydrogen Monofluorophosphates and Basic Monofluorophosphates with Alkali Metal and N-containing Cations |
|
a, b, c, |
lattice constants and angles |
|
A |
hydrogen acceptor of the hydrogen bond |
|
Å |
Ångstrom, 10 pm, 10-10 m |
|
aq |
aqueous |
|
avg. |
average |
|
calcd |
calculated |
|
Cs/NH4 |
Cs3(NH4)2(HPO3F)3(PO3F)2 |
|
½D + ½A |
½ hydrogen donor and ½ hydrogen acceptor |
|
d |
bond length |
|
D |
hydrogen donor of the hydrogen bond |
|
Diet |
diethyl ammonium hydrogen monofluorophosphate |
|
di or disd |
disordered |
|
DTA |
differential thermal analysis |
|
DTG |
differential thermogravimetric analysis |
|
Et |
ethyl group, -CH2CH3 |
|
EtOH |
ethanol |
|
Et2O |
diethyl ether |
|
GooF |
goodness of fit defined as GooF = S ={ |
|
(H)PO3F |
hydrogen monofluorophosphate or monofluorophosphate |
|
H(H)PO3F |
hydrogen atom of OH group in the (H)PO3F tetrahedron |
|
HN |
hydrogen atom on nitrogen |
|
IC |
ion current |
|
M |
Na+, K+, Rb+, Cs+, or NH4+, unless otherwise defined |
|
Me |
methyl group, -CH3 |
|
med |
medium |
|
MeOH |
methanol |
|
Na/[NMe4] |
Na5[NMe4](PO3F)3·18H2O |
|
N,N´-dmu |
N,N´-dimethyl urea |
|
N,N´-dmuH+ |
N,N´-dimethyl uronium cation, {HOC[NH(CH3)]2}+ |
|
OA |
hydrogen acceptor oxygen atom |
|
Occ. |
occupancy |
|
OD |
hydrogen donor oxygen atom |
|
Ow |
oxyge. atom of crystal water |
|
O(w) |
oxygen atom of crystal water or (H)PO3F tetrahedron |
|
PE |
polyethylene |
|
PipzH22+ |
piperazinium cation, [NH2(CH2CH2)2NH2]2+ |
|
Pipz |
piperazinium hydrogen monofluorophosphate |
|
PTA |
pulse thermal analysis |
|
R1 |
residual factor defined as R1 = |
|
RT |
room temperature |
|
Sect. |
section |
|
STA |
simultaneous thermal analysis (DG, DTA, TG) |
|
TG |
thermogravimetry |
|
wR2 |
residual factor defined as wR2 = { |
|
V |
unit cell volume |
|
VF |
total fluorine bond valency |
|
X |
oxygen or fluorine atom, unless defined otherwise |
|
XRD |
X-ray powder diffraction |
|
Z |
number of formula units in the cell |
|
µ |
absorption coefficient |
|
|
density, calculated |
|
|
bond angle |
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