2016-06-01Zeitschriftenartikel
The binuclear nickel center in the A-cluster of acetyl-CoA synthase (ACS) and two biomimetic dinickel complexes studied by X-ray absorption and emission spectroscopy
Schrapers, Peer; Mebs, Stefan; Ilina, Y.; Warner, D. S.; Wörmann, C.; Schuth, Nils; Kositzki, Ramona; Dau, Holger; Limberg, Christian; Dobbek, Holger; Haumann, Michael
Acetyl-CoA synthase (ACS) is involved in the bacterial carbon oxide conversion pathway. The binuclear nickel sites in ACS enzyme and two biomimetic synthetic compounds containing a Ni(II)Ni(II) unit (1 and 2) were compared ...