2023-02-03Zeitschriftenartikel
Magnetic Anisotropy and Relaxation of Pseudotetrahedral [N2O2] Bis‐Chelate Cobalt(II) Single‐Ion Magnets Controlled by Dihedral Twist Through Solvomorphism
Pohle, Maximilian; Böhme, Michael; Lohmiller, Thomas; Ziegenbalg, Sven; Blechschmidt, Louis; Görls, Helmar; Schnegg, Alexander; Plass, Winfried
The methanol solvomorph 1 ⋅ 2MeOH of the cobalt(II) complex [Co(LSal,2−Ph)2] (1) with the sterically demanding Schiff-base ligand 2-(([1,1′-biphenyl]-2-ylimino)methyl)phenol (HLSal,2−Ph) shows the thus far largest dihedral ...