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2015-05-01Zeitschriftenartikel DOI: 10.1039/c5cc02811f
Gating the photochromism of an azobenzene by strong host–guest interactions in a divalent pseudo[2]rotaxane
Lohse, Mirko
Nowosinski, Karol
Traulsen, Nora L.
Achazi, Andreas J.
Krbek, Larissa K. S. von
Paulus, Beate
Schalley, Christoph A.
Hecht, Stefan cc
Institut für Chemie
The ability of an E-configured azobenzene guest to undergo photoisomerisation is controlled by the presence of a complementary host. Addition of base/acid allowed for a weakening/strengthening of the interactions in the divalent pseudo[2]rotaxane complex and hence could switch on/off photochromic activity.
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DOI
10.1039/c5cc02811f
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https://doi.org/10.1039/c5cc02811f
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<a href="https://doi.org/10.1039/c5cc02811f">https://doi.org/10.1039/c5cc02811f</a>