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2018-12-03Zeitschriftenartikel DOI: 10.3390/inorganics6040128
Fluorolytic Sol−Gel Synthesis of Nanometal Fluorides: Accessing New Materials for Optical Applications
dc.contributor.authorScheurell, Kerstin
dc.contributor.authorKemnitz, Erhard
dc.date.accessioned2019-09-17T10:53:01Z
dc.date.available2019-09-17T10:53:01Z
dc.date.issued2018-12-03none
dc.date.updated2019-08-01T11:59:12Z
dc.identifier.urihttp://edoc.hu-berlin.de/18452/21277
dc.description.abstractThe potential of fluorolytic sol–gel synthesis for a wide variety of applications in the field of optical materials is reviewed. Based on the fluorolytic sol–gel synthesis of nanometal fluorides, sols of complex fluorometalates have become available that exhibit superior optical properties over known classical binary metal fluorides as, for instance, magnesium fluoride, calcium fluoride, or strontium fluoride, respectively. The synthesis of transparent sols of magnesium fluoroaluminates of the general composition MgxAlFy, and fluoroperovskites, [K1−xNax]MgF3, is reported. Antireflective coatings fabricated from MgF2, CaF2, MgxAlFy, and [K1−xNax]MgF3 sols and their relevant properties are comprehensively described. Especially the heavier alkaline earth metal fluorides and the fluorperovskites crystallizing in a cubic crystal structure are excellent hosts for rare earth (RE) metals. Thus, the second chapter reflects the synthesis approach and the properties of luminescent systems based on RE-doped alkaline earth metal fluorides and [K1−xNax]MgF3 phases.eng
dc.language.isoengnone
dc.publisherHumboldt-Universität zu Berlin
dc.rights(CC BY 4.0) Attribution 4.0 Internationalger
dc.rights.urihttps://creativecommons.org/licenses/by/4.0/
dc.subjectnanometal fluorideseng
dc.subjectsol–gel synthesiseng
dc.subjectantireflective coatingseng
dc.subjectluminescent materialseng
dc.subject.ddc540 Chemie und zugeordnete Wissenschaftennone
dc.titleFluorolytic Sol−Gel Synthesis of Nanometal Fluorides: Accessing New Materials for Optical Applicationsnone
dc.typearticle
dc.identifier.urnurn:nbn:de:kobv:11-110-18452/21277-8
dc.identifier.doi10.3390/inorganics6040128none
dc.identifier.doihttp://dx.doi.org/10.18452/20552
dc.type.versionpublishedVersionnone
local.edoc.container-titleInorganicsnone
local.edoc.pages19none
local.edoc.type-nameZeitschriftenartikel
local.edoc.institutionMathematisch-Naturwissenschaftliche Fakultätnone
local.edoc.container-typeperiodical
local.edoc.container-type-nameZeitschrift
local.edoc.container-publisher-nameMDPInone
local.edoc.container-publisher-placeBaselnone
local.edoc.container-volume6none
local.edoc.container-issue4none
dc.description.versionPeer Reviewednone
local.edoc.container-articlenumber128none
dc.identifier.eissn2304-6740
local.edoc.affiliationScheurell, Kerstin; Humboldt-Universität zu Berlin, Department of Chemistry, Brook-Taylor-Str. 2, D-12489 Berlin, Germany,none
local.edoc.affiliationKemnitz, Erhard; Humboldt-Universität zu Berlin, Department of Chemistry, Brook-Taylor-Str. 2, D-12489 Berlin, Germany,none

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