Preparation of NHC Stabilized Al(III)fluorides: Fluorination of [(SIMes)AlMe3] with SF4 or Me3SnF
dc.contributor.author | Tomar, Pooja | |
dc.contributor.author | Braun, Thomas | |
dc.contributor.author | Kemnitz, Erhard | |
dc.date.accessioned | 2019-11-27T12:08:04Z | |
dc.date.available | 2019-11-27T12:08:04Z | |
dc.date.issued | 2019-11-13 | none |
dc.identifier.uri | http://edoc.hu-berlin.de/18452/21579 | |
dc.description.abstract | Various reaction routes have been developed to synthesize the N‐heterocyclic carbene (NHC) stabilized Al(III) fluorides [(SIMes)Al(F)3] (2) and [(SIMes)Al(F)Me2] (3) through fluorination of [(SIMes)AlMe3] (1) (SIMes: 1,3‐bis(2,4,6‐trimethylphenyl)‐imidazolidin‐2‐ylidene) with fluorinating agents such as SF4, SF6 and Me3SnF. The reactivity of 2 was investigated towards a F/Cl exchange reaction by treating it with Me3SiCl. | eng |
dc.language.iso | eng | none |
dc.publisher | Humboldt-Universität zu Berlin | |
dc.rights | (CC BY-NC-ND 4.0) Attribution-NonCommercial-NoDerivatives 4.0 International | ger |
dc.rights.uri | https://creativecommons.org/licenses/by-nc-nd/4.0/ | |
dc.subject.ddc | 540 Chemie und zugeordnete Wissenschaften | none |
dc.title | Preparation of NHC Stabilized Al(III)fluorides: Fluorination of [(SIMes)AlMe3] with SF4 or Me3SnF | none |
dc.type | article | |
dc.identifier.urn | urn:nbn:de:kobv:11-110-18452/21579-9 | |
dc.identifier.doi | http://dx.doi.org/10.18452/20845 | |
dc.type.version | publishedVersion | none |
local.edoc.pages | 5 | none |
local.edoc.type-name | Zeitschriftenartikel | |
local.edoc.container-type | periodical | |
local.edoc.container-type-name | Zeitschrift | |
dc.description.version | Peer Reviewed | none |
dc.identifier.eissn | 1099-0682 | |
dcterms.bibliographicCitation.doi | 10.1002/ejic.201900921 | |
dcterms.bibliographicCitation.journaltitle | European journal of inorganic chemistry | none |
dcterms.bibliographicCitation.volume | 2019 | none |
dcterms.bibliographicCitation.issue | 44 | none |
dcterms.bibliographicCitation.originalpublishername | Wiley-VCH | none |
dcterms.bibliographicCitation.originalpublisherplace | Weinheim | none |
dcterms.bibliographicCitation.pagestart | 4735 | none |
dcterms.bibliographicCitation.pageend | 4739 | none |
bua.department | Mathematisch-Naturwissenschaftliche Fakultät | none |