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2020-02-28Zeitschriftenartikel DOI: 10.18452/21329
Evaluating the Solvent Stark Effect from Temperature-Dependent Solvatochromic Shifts of Anthracene
dc.contributor.authorJanz, Timais
dc.contributor.authorGüterbock, Manuel
dc.contributor.authorMüller, Fabian
dc.contributor.authorQuick, Martin
dc.contributor.authorIoffe, Ilya N.
dc.contributor.authorBischoff, Florian A.
dc.contributor.authorKovalenko, Sergey A.
dc.date.accessioned2020-04-02T09:01:19Z
dc.date.available2020-04-02T09:01:19Z
dc.date.issued2020-02-28none
dc.identifier.urihttp://edoc.hu-berlin.de/18452/22069
dc.description.abstractThe solvent Stark effect on the spectral shifts of anthracene is studied with temperature‐dependent solvatochromic measurements. The Stark contribution ΔvStark to the absorption shift Δvp in polar solvents is measured to be ΔvStark=(53±35) cm−1, in reasonable agreement with dielectric continuum theory estimate of 28 cm−1, whereas the major shift Δvp∼300 cm−1 presumably originates from the solute quadrupole. We pay attention to the accurate correction of Δvp for the nonpolar contribution that is crucial when the shifts are modest in magnitude.eng
dc.language.isoengnone
dc.publisherHumboldt-Universität zu Berlin
dc.rights(CC BY 4.0) Attribution 4.0 Internationalger
dc.rights.urihttps://creativecommons.org/licenses/by/4.0/
dc.subjectanthraceneeng
dc.subjectcomputational chemistryeng
dc.subjectsolvatochromic shiftseng
dc.subjectsolvent Stark effecteng
dc.subjectsolute polarizabilitieseng
dc.subject.ddc540 Chemie und zugeordnete Wissenschaftennone
dc.titleEvaluating the Solvent Stark Effect from Temperature-Dependent Solvatochromic Shifts of Anthracenenone
dc.typearticle
dc.identifier.urnurn:nbn:de:kobv:11-110-18452/22069-0
dc.identifier.doihttp://dx.doi.org/10.18452/21329
dc.type.versionpublishedVersionnone
local.edoc.pages6none
local.edoc.type-nameZeitschriftenartikel
local.edoc.container-typeperiodical
local.edoc.container-type-nameZeitschrift
dc.description.versionPeer Reviewednone
dc.identifier.eissn1439-7641
dcterms.bibliographicCitation.doi10.1002/cphc.202000010
dcterms.bibliographicCitation.journaltitleChemPhysChemnone
dcterms.bibliographicCitation.volume21none
dcterms.bibliographicCitation.issue7none
dcterms.bibliographicCitation.originalpublishernameWiley-VCHnone
dcterms.bibliographicCitation.originalpublisherplaceWeinheimnone
dcterms.bibliographicCitation.pagestart610none
dcterms.bibliographicCitation.pageend615none
bua.departmentMathematisch-Naturwissenschaftliche Fakultätnone

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