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2021-01-28Zeitschriftenartikel DOI: 10.1002/anie.202015833
Accessing the Next Generation of Synthetic Mussel‐Glue Polymers via Mussel‐Inspired Polymerization
dc.contributor.authorKrüger, Jana M.
dc.contributor.authorBörner, Hans G.
dc.date.accessioned2021-08-19T10:51:00Z
dc.date.available2021-08-19T10:51:00Z
dc.date.issued2021-01-28none
dc.date.updated2021-06-14T13:29:28Z
dc.identifier.issn1433-7851
dc.identifier.urihttp://edoc.hu-berlin.de/18452/23857
dc.description.abstractThe formation of cysteinyldopa as biogenic connectivity in proteins is used to inspire a chemical pathway toward mussel-adhesive mimics. The mussel-inspired polymerization (MIPoly) exploits the chemically diverse family of bisphenol monomers that is oxidizable with 2-iodoxybenzoic acid to give bisquinones. Those react at room temperature with dithiols in Michael-type polyadditions, which leads to polymers with thiol–catechol connectivities (TCC). A set of TCC polymers proved adhesive behavior even on challenging poly(propylene) substrates, where they compete with commercial epoxy resins in dry adhesive strength. MIPoly promises facile scale up and exhibits high modularity to tailor adhesives, as proven on a small library where one candidate showed wet adhesion on aluminum substrates in both water and sea water models.eng
dc.description.sponsorshipVerband der Chemischen Industrie http://dx.doi.org/10.13039/100007215
dc.description.sponsorshipDeutsche Forschungsgemeinschaft http://dx.doi.org/10.13039/501100001659
dc.language.isoengnone
dc.publisherHumboldt-Universität zu Berlin
dc.rights(CC BY-NC-ND 4.0) Attribution-NonCommercial-NoDerivatives 4.0 Internationalger
dc.rights.urihttps://creativecommons.org/licenses/by-nc-nd/4.0/
dc.subjectadhesive libraryeng
dc.subjectBiomimetic adhesiveseng
dc.subjectDopa mimicseng
dc.subjectMussel-inspired glueeng
dc.subject.ddc540 Chemie und zugeordnete Wissenschaftennone
dc.subject.ddc660 Chemische Verfahrenstechnik und verwandte Technologiennone
dc.titleAccessing the Next Generation of Synthetic Mussel‐Glue Polymers via Mussel‐Inspired Polymerizationnone
dc.typearticle
dc.identifier.urnurn:nbn:de:kobv:11-110-18452/23857-1
dc.identifier.doi10.1002/anie.202015833none
dc.identifier.doihttp://dx.doi.org/10.18452/23238
dc.type.versionpublishedVersionnone
local.edoc.container-titleAngewandte Chemie : a journal of the Gesellschaft Deutscher Chemikernone
local.edoc.pages6none
local.edoc.type-nameZeitschriftenartikel
local.edoc.institutionMathematisch-Naturwissenschaftliche Fakultätnone
local.edoc.container-typeperiodical
local.edoc.container-type-nameZeitschrift
local.edoc.container-publisher-nameWiley-VCHnone
local.edoc.container-publisher-placeWeinheimnone
local.edoc.container-volume60none
local.edoc.container-issue12none
local.edoc.container-firstpage6408none
local.edoc.container-lastpage6413none
dc.description.versionPeer Reviewednone
dc.identifier.eissn1521-3773
local.edoc.affiliationKrüger, Jana M.: Laboratory for Organic Synthesis of Functional Systems, Department of Chemistry, Humboldt-Universität zu Berlin, Brook-Taylor-Strasse 2, 12489 Berlin, Germanynone
local.edoc.affiliationBörner, Hans G.: Laboratory for Organic Synthesis of Functional Systems, Department of Chemistry, Humboldt-Universität zu Berlin, Brook-Taylor-Strasse 2, 12489 Berlin, Germanynone

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