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2020-05-19Zeitschriftenartikel DOI: 10.18452/23698
Synthesis and Reactivity of Iridium(I) Fluorido Complexes: Oxidative Addition of SF4 at trans-[Ir(F)(CO)(PEt3)2]
dc.contributor.authorPfister, Nils
dc.contributor.authorBui, Minh
dc.contributor.authorBraun, Thomas
dc.contributor.authorWittwer, Philipp
dc.contributor.authorAhrens, Mike
dc.date.accessioned2021-11-24T14:45:31Z
dc.date.available2021-11-24T14:45:31Z
dc.date.issued2020-05-19none
dc.identifier.other10.1002/zaac.202000026
dc.identifier.urihttp://edoc.hu-berlin.de/18452/24361
dc.description.abstractThe facile access to the Vaska type fluorido complexes trans-[Ir(F)(CO)(PR3)2] [6: R = Et, 7: R = Ph, 8: R = iPr, 9: R = Cy, 10: R = tBu] was achieved by halide exchange at trans-[Ir(Cl)(CO)(PR3)2] (1–5) with Me4NF. Furthermore, the reaction of complex 6 with SF4 gave cis,trans-[Ir(F)2(SF3)(CO)(PEt3)2] (11), whereas 8–10 did not react. Reactivity studies revealed that 11 can selectively be manipulated at the sulfur atom by hydrolysis or fluoride abstraction to give cis,trans-[Ir(F)2(SOF)(CO)(PEt3)2] (12) and cis,trans-[Ir(F)2(SF2)(CO)(PEt3)2][AsF6] (13), respectively.eng
dc.language.isoengnone
dc.publisherHumboldt-Universität zu Berlin
dc.rights(CC BY-NC-ND 4.0) Attribution-NonCommercial-NoDerivatives 4.0 Internationalger
dc.rights.urihttps://creativecommons.org/licenses/by-nc-nd/4.0/
dc.subjectSulfur fluorideseng
dc.subjectIridiumeng
dc.subjectS–F activationeng
dc.subjectFluorido complexeseng
dc.subjectSulfur tetrafluorideeng
dc.subject.ddc540 Chemienone
dc.titleSynthesis and Reactivity of Iridium(I) Fluorido Complexes: Oxidative Addition of SF4 at trans-[Ir(F)(CO)(PEt3)2]none
dc.typearticle
dc.identifier.urnurn:nbn:de:kobv:11-110-18452/24361-9
dc.identifier.doihttp://dx.doi.org/10.18452/23698
dc.type.versionpublishedVersionnone
local.edoc.container-titleZeitschrift für anorganische und allgemeine Chemienone
local.edoc.pages8none
local.edoc.type-nameZeitschriftenartikel
local.edoc.institutionMathematisch-Naturwissenschaftliche Fakultätnone
local.edoc.container-typeperiodical
local.edoc.container-type-nameZeitschrift
local.edoc.container-publisher-nameWiley-VCHnone
local.edoc.container-publisher-placeWeinheimnone
local.edoc.container-volume646none
local.edoc.container-issue13none
local.edoc.container-firstpage808none
local.edoc.container-lastpage815none
dc.description.versionPeer Reviewednone
dc.identifier.eissn1521-3749

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