A HF Loaded Lewis-Acidic Aluminium Chlorofluoride for Hydrofluorination Reactions
Mathematisch-Naturwissenschaftliche Fakultät
The very strong Lewis acid aluminium chlorofluoride
(ACF) was loaded with anhydrous HF. The interaction
between the surface of the catalyst and HF was investigated
using a variety of characterization methods, which revealed
the formation of polyfluorides. Moreover, the reactivity of
the HF-loaded ACF towards the hydrofluorination of alkynes
was studied.
