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2021-11-16Zeitschriftenartikel DOI: 10.3390/cryst11111397
Elastic Flexibility in an Optically Active Naphthalidenimine-Based Single Crystal
dc.contributor.authorFeiler, Torvid
dc.contributor.authorMichalchuk, Adam
dc.contributor.authorSchröder, Vincent
dc.contributor.authorList-Kratochvil, Emil J.W.
dc.contributor.authorEmmerling, Franziska
dc.contributor.authorBhattacharya, Biswajit
dc.date.accessioned2022-01-13T12:50:22Z
dc.date.available2022-01-13T12:50:22Z
dc.date.issued2021-11-16none
dc.date.updated2021-12-01T20:53:02Z
dc.identifier.urihttp://edoc.hu-berlin.de/18452/24565
dc.description.abstractOrganic single crystals that combine mechanical flexibility and optical properties are important for developing flexible optical devices, but examples of such crystals remain scarce. Both mechanical flexibility and optical activity depend on the underlying crystal packing and the nature of the intermolecular interactions present in the solid state. Hence, both properties can be expected to be tunable by small chemical modifications to the organic molecule. By incorporating a chlorine atom, a reportedly mechanically flexible crystal of (E)-1-(4-bromo-phenyl)iminomethyl-2-hydroxyl-naphthalene (BPIN) produces (E)-1-(4-bromo-2-chloro-phenyl)iminomethyl-2-hydroxyl-naphthalene (BCPIN). BCPIN crystals show elastic bending similar to BPIN upon mechanical stress, but exhibit a remarkable difference in their optical properties as a result of the chemical modification to the backbone of the organic molecule. This work thus demonstrates that the optical properties and mechanical flexibility of molecular materials can, in principle, be tuned independently.eng
dc.language.isoengnone
dc.publisherHumboldt-Universität zu Berlin
dc.rights(CC BY 4.0) Attribution 4.0 Internationalger
dc.rights.urihttps://creativecommons.org/licenses/by/4.0/
dc.subjectcrystal engineeringeng
dc.subjectmolecular crystaleng
dc.subjectmechanical propertyeng
dc.subjectelastic crystaleng
dc.subject.ddc540 Chemie und zugeordnete Wissenschaftennone
dc.titleElastic Flexibility in an Optically Active Naphthalidenimine-Based Single Crystalnone
dc.typearticle
dc.identifier.urnurn:nbn:de:kobv:11-110-18452/24565-4
dc.identifier.doi10.3390/cryst11111397none
dc.identifier.doihttp://dx.doi.org/10.18452/23934
dc.type.versionpublishedVersionnone
local.edoc.container-titleCrystals : open access journalnone
local.edoc.pages9none
local.edoc.type-nameZeitschriftenartikel
local.edoc.institutionMathematisch-Naturwissenschaftliche Fakultätnone
local.edoc.container-typeperiodical
local.edoc.container-type-nameZeitschrift
local.edoc.container-publisher-nameMDPInone
local.edoc.container-publisher-placeBaselnone
local.edoc.container-volume11none
local.edoc.container-issue11none
dc.description.versionPeer Reviewednone
local.edoc.container-articlenumber1397none
dc.identifier.eissn2073-4352

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