Browsing Artikel und Monographien by Subject "calixarene"

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2021-03-29Zeitschriftenartikel

Binding of a TlCl Entity by a Tetragold Tetramercaptothiacalixarene Metalloligand via Metallophilic Interactions

Frank, Nicolas; Pryjomska-Ray, Iweta; Grubert, Lutz; Hecht, Stefan; Usvyat, Denis; Limberg, Christian

p-tert-Butyltetramercaptotetrathiacalix[4]arene was used as a coordination platform to synthesize and investigate gold(I) complexes with varying nuclearity. Aiming at the corresponding tetranuclear complex through salt ...
2020-03-03Zeitschriftenartikel

Mercaptothiacalixarenes Steer 24 Copper(I) Centers to form a Hollow‐Sphere Structure Featuring Cu2S2 Motifs with Exceptionally Short Cu⋅⋅⋅Cu Distances

Frank, Nicolas; Dallmann, André; Braun-Cula, Beatrice; Herwig, Christian; Limberg, Christian

Tetramercaptotetrathiacalix[4]arene (LH4) can be used as a coordination platform to bind four CuI ions at the thiolate and thioether S atoms. Donor ligands such as phosphanes can stabilize the resulting [LCu4] units, which ...