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InstitutionMathematisch-Naturwissenschaftliche Fakultät (6)Kultur-, Sozial- und Bildungswissenschaftliche Fakultät (1)DDC
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InstitutionMathematisch-Naturwissenschaftliche Fakultät (6)Kultur-, Sozial- und Bildungswissenschaftliche Fakultät (1)DDC
540 Chemie und zugeordnete Wissenschaften (7)
660 Chemische Verfahrenstechnik (7)
530 Physik (1)
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2019-08-13Zeitschriftenartikel
A π‐Conjugated, Covalent Phosphinine Framework 
Huang, Jieyang; Tarabek, Jan; Kulkarni, Ranjit; Wang, Cui; Dracinsky, Martin; Smales, Glen; Tian, Yu; Ren, Shijie; Pauw, Brian; Resch-Genger, Ute; Bojdys, Michael
Structural modularity of polymer frameworks is a key advantage of covalent organic polymers, however, only C, N, O, Si, and S have found their way into their building blocks so far. Here, the toolbox available to polymer ...
2020-01-02Zeitschriftenartikel
Molecular Bottle Brushes with Positioned Selenols 
Extending the Toolbox of Oxidative Single Polymer Chain Folding with Conformation Analysis by Atomic Force Microscopy
Schué, Emmanuelle; Kopyshev, Alexey; Lutz, Jean-Francois; Börner, Hans G.
A synthesis route to controlled and dynamic single polymer chain folding is reported. Sequence‐controlled macromolecules containing precisely located selenol moieties within a polymer chain are synthesized. Oxidation of ...
2020-04-21Zeitschriftenartikel
A Novel Visible Range FRET Probe for Monitoring Acid Sphingomyelinase Activity in Living Cells 
Kappe, Christian; Mohamed, Zainelabdeen H.; Naser, Eyad; Carpinteiro, Alexander; Arenz, Christoph
Activity of acid sphingomyelinase has been implicated in a number of diseases like acute lung injury, sepsis or metastasis of melanoma cells. Here, we present a sphingomyelinase FRET probe based on FAM/BODIPY dyes for ...
2020-03-26Zeitschriftenartikel
Mechanistic Insights into the Triplet Sensitized Photochromism of Diarylethenes 
Fredrich, Sebastian; Morack, Tobias; Sliwa, Michel; Hecht, Stefan
Operating photoswitchable molecules repetitively and reliably is crucial for most of their applications, in particular in (opto)electronic devices, and related to reversibility and fatigue resistance, which both critically ...
2019-09-19Zeitschriftenartikel
Oxygen-Depleted Calixarenes as Ligands for Molecular Models of Galactose Oxidase 
Keck, Matthias; Hoof, Santina; Herwig, Christian; Vigalok, Arkadi; Limberg, Christian
A calix[4]arene ligand, in which two of the phenol functions are replaced by pyrazole units has been employed to mimic the His2–Tyr2 (His: histidine, Tyr: tyrosine) ligand sphere within the active site of the galactose ...
2020-08-13Zeitschriftenartikel
Enhancing Tris(pyrazolyl)borate-Based Models of Cysteine/ Cysteamine Dioxygenases through Steric Effects 
Increased Reactivities, Full Product Characterization and Hints to Initial Superoxide Formation
Müller, Lars; Hoof, Santina; Keck, Matthias; Herwig, Christian; Limberg, Christian
The design of biomimetic model complexes for the cysteine dioxygenase (CDO) and cysteamine dioxygenase (ADO) is reported, where the 3‐His coordination of the iron ion is simulated by three pyrazole donors of a trispyrazolyl ...
2020-08-04Zeitschriftenartikel
Wood and the Activity of Dead Tissue 
Eder, Michaela; Schäffner, Wolfgang; Burgert, Ingo; Fratzl, Peter
Wood is a prototypical biological material, which adapts to mechanical requirements. The microarchitecture of cellulose fibrils determines the mechanical properties of woody materials, as well as their actuation properties, ...
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