Chlorodefluorination of Fluoromethanes and Fluoroolefins at a Lewis Acidic Aluminum Fluoride
dc.contributor.author | Pan, Xinzi | |
dc.contributor.author | Talavera, Maria | |
dc.contributor.author | Scholz, Gudrun | |
dc.contributor.author | Braun, Thomas | |
dc.date.accessioned | 2022-07-06T11:49:03Z | |
dc.date.available | 2022-07-06T11:49:03Z | |
dc.date.issued | 2022-03-19 | none |
dc.date.updated | 2022-06-14T21:37:30Z | |
dc.identifier.uri | http://edoc.hu-berlin.de/18452/25628 | |
dc.description.abstract | Chlorodefluorination reactions of fluoromethanes and fluoroolefins catalysed by the highly Lewis acidic nanoscopic aluminum chlorofluoride (ACF, AlClxF3−x, x≈0.05–0.3) in the presence of ClSiEt3 were studied. Both fluoromethanes and fluoroolefins convert under mild reaction conditions by fluorine-chlorine exchange steps into chlorinated fluoro derivatives. MAS NMR studies provided information on the interaction of silanes and hexafluoropropene with the ACF surface. | eng |
dc.description.sponsorship | CRC 1349 | |
dc.description.sponsorship | Deutsche Forschungsgemeinschaft (DFG), German Research Foundation | |
dc.description.sponsorship | Deutsche Forschungsgemeinschaft http://dx.doi.org/10.13039/501100001659 | |
dc.description.sponsorship | Chinese Scholarship Council | |
dc.language.iso | eng | none |
dc.publisher | Humboldt-Universität zu Berlin | |
dc.rights | (CC BY-NC-ND 4.0) Attribution-NonCommercial-NoDerivatives 4.0 International | ger |
dc.rights.uri | https://creativecommons.org/licenses/by-nc-nd/4.0/ | |
dc.subject | aluminum | eng |
dc.subject | C−F activation | eng |
dc.subject | chlorodefluorination | eng |
dc.subject | fluorine | eng |
dc.subject | Lewis acids | eng |
dc.subject.ddc | 540 Chemie und zugeordnete Wissenschaften | none |
dc.title | Chlorodefluorination of Fluoromethanes and Fluoroolefins at a Lewis Acidic Aluminum Fluoride | none |
dc.type | article | |
dc.identifier.urn | urn:nbn:de:kobv:11-110-18452/25628-0 | |
dc.identifier.doi | http://dx.doi.org/10.18452/24947 | |
dc.type.version | publishedVersion | none |
local.edoc.pages | 7 | none |
local.edoc.type-name | Zeitschriftenartikel | |
local.edoc.container-type | periodical | |
local.edoc.container-type-name | Zeitschrift | |
dc.description.version | Peer Reviewed | none |
dc.identifier.eissn | 1867-3899 | |
dcterms.bibliographicCitation.doi | 10.1002/cctc.202200029 | none |
dcterms.bibliographicCitation.journaltitle | ChemCatChem | none |
dcterms.bibliographicCitation.volume | 14 | none |
dcterms.bibliographicCitation.issue | 10 | none |
dcterms.bibliographicCitation.articlenumber | e202200029 | none |
dcterms.bibliographicCitation.originalpublishername | WILEY-VCH Verlag | none |
dcterms.bibliographicCitation.originalpublisherplace | Weinheim | none |
bua.department | Mathematisch-Naturwissenschaftliche Fakultät | none |