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2022-03-19Zeitschriftenartikel DOI: 10.1002/cctc.202200029
Chlorodefluorination of Fluoromethanes and Fluoroolefins at a Lewis Acidic Aluminum Fluoride
dc.contributor.authorPan, Xinzi
dc.contributor.authorTalavera, Maria
dc.contributor.authorScholz, Gudrun
dc.contributor.authorBraun, Thomas
dc.date.accessioned2022-07-06T11:49:03Z
dc.date.available2022-07-06T11:49:03Z
dc.date.issued2022-03-19none
dc.date.updated2022-06-14T21:37:30Z
dc.identifier.urihttp://edoc.hu-berlin.de/18452/25628
dc.description.abstractChlorodefluorination reactions of fluoromethanes and fluoroolefins catalysed by the highly Lewis acidic nanoscopic aluminum chlorofluoride (ACF, AlClxF3−x, x≈0.05–0.3) in the presence of ClSiEt3 were studied. Both fluoromethanes and fluoroolefins convert under mild reaction conditions by fluorine-chlorine exchange steps into chlorinated fluoro derivatives. MAS NMR studies provided information on the interaction of silanes and hexafluoropropene with the ACF surface.eng
dc.description.sponsorshipCRC 1349
dc.description.sponsorshipDeutsche Forschungsgemeinschaft (DFG), German Research Foundation
dc.description.sponsorshipDeutsche Forschungsgemeinschaft http://dx.doi.org/10.13039/501100001659
dc.description.sponsorshipChinese Scholarship Council
dc.language.isoengnone
dc.publisherHumboldt-Universität zu Berlin
dc.rights(CC BY-NC-ND 4.0) Attribution-NonCommercial-NoDerivatives 4.0 Internationalger
dc.rights.urihttps://creativecommons.org/licenses/by-nc-nd/4.0/
dc.subjectaluminumeng
dc.subjectC−F activationeng
dc.subjectchlorodefluorinationeng
dc.subjectfluorineeng
dc.subjectLewis acidseng
dc.subject.ddc540 Chemie und zugeordnete Wissenschaftennone
dc.titleChlorodefluorination of Fluoromethanes and Fluoroolefins at a Lewis Acidic Aluminum Fluoridenone
dc.typearticle
dc.identifier.urnurn:nbn:de:kobv:11-110-18452/25628-0
dc.identifier.doi10.1002/cctc.202200029none
dc.identifier.doihttp://dx.doi.org/10.18452/24947
dc.type.versionpublishedVersionnone
local.edoc.container-titleChemCatChemnone
local.edoc.pages7none
local.edoc.type-nameZeitschriftenartikel
local.edoc.institutionMathematisch-Naturwissenschaftliche Fakultätnone
local.edoc.container-typeperiodical
local.edoc.container-type-nameZeitschrift
local.edoc.container-publisher-nameWILEY-VCH Verlagnone
local.edoc.container-publisher-placeWeinheimnone
local.edoc.container-volume14none
local.edoc.container-issue10none
dc.description.versionPeer Reviewednone
local.edoc.container-articlenumbere202200029none
dc.identifier.eissn1867-3899

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