Nonperturbative modeling of fifth-order coherent multidimensional spectroscopy in light harvesting antennas
Mathematisch-Naturwissenschaftliche Fakultät
Recent advances in coherent multidimensional spectroscopy have boosted interest in exciton coherences in light harvesting complexes. We present nonperturbative calculations of two-dimensional (2D) electronic spectroscopy from a fifth-order phase-matching direction. The calculations show clear patterns that correspond to the electronic structure of one- and two-exciton manifolds of a Fenna–Matthews–Olsson light harvesting complex. Such signals can provide new information about the coherent properties of antenna pigment protein complexes.
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