Now showing items 11-14 of 14
A π‐Conjugated, Covalent Phosphinine Framework
Structural modularity of polymer frameworks is a key advantage of covalent organic polymers, however, only C, N, O, Si, and S have found their way into their building blocks so far. Here, the toolbox available to polymer ...
Enhancing Tris(pyrazolyl)borate-Based Models of Cysteine/ Cysteamine Dioxygenases through Steric Effects
The design of biomimetic model complexes for the cysteine dioxygenase (CDO) and cysteamine dioxygenase (ADO) is reported, where the 3‐His coordination of the iron ion is simulated by three pyrazole donors of a trispyrazolyl ...
Structural Determination of an Unusual CuI‐Porphyrin‐π‐Bond in a Hetero‐Pacman Cu‐Zn‐Complex
The synthesis and characterization of a hetero-dinuclear compound is presented, in which a copper(I)trishistidine type coordination unit is positioned directlyabove a zinc porphyrin unit. The close distance betweenthe two ...
Mechanistic Insights into the Triplet Sensitized Photochromism of Diarylethenes
Operating photoswitchable molecules repetitively and reliably is crucial for most of their applications, in particular in (opto)electronic devices, and related to reversibility and fatigue resistance, which both critically ...