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2024-02-08Zeitschriftenartikel DOI: 10.18452/28553
Isolation of an Osmium(III) Hydrido Complex
dc.contributor.authorAlizadeh, Niyaz
dc.contributor.authorAbbenseth, Josh
dc.contributor.authorBete, Sarah
dc.contributor.authorFinger, Markus
dc.contributor.authorOtte, Matthias
dc.contributor.authorWürtele, Christian
dc.contributor.authorSchneider, Sven
dc.date.accessioned2024-04-22T15:54:28Z
dc.date.available2024-04-22T15:54:28Z
dc.date.issued2024-02-08none
dc.date.updated2024-04-16T08:22:04Z
dc.identifier.issn0044-2313
dc.identifier.urihttp://edoc.hu-berlin.de/18452/29187
dc.description.abstractSynthesis and characterization of [OsH(PNP)(bipy)]+ (PNP=N(CHCHPtBu2)2) are reported, as the second osmium(III) hydrido complex next to [OsH(en)2(py)]2+. While the osmium(II) precursor, [OsH(PNP)(bipy)], exhibits two reversible oxidations in the cyclic voltammogram, the product from 2‐electron oxidation could not be isolated due to rapid decay. Thermochemical examinations attribute the stability of the osmium(III) hydride to both thermodynamic and kinetic reasons. In contrast, the high estimated acidity of [OsH(PNP)(bipy)]2+ presumably leads to rapid decay.eng
dc.description.sponsorshipDeutsche Forschungsgemeinschaft http://dx.doi.org/10.13039/501100001659
dc.description.sponsorshipFonds der Chemischen Industrie http://dx.doi.org/10.13039/100018992
dc.language.isoengnone
dc.publisherHumboldt-Universität zu Berlin
dc.rights(CC BY-NC 4.0) Attribution-NonCommercial 4.0 Internationalger
dc.rights.urihttps://creativecommons.org/licenses/by-nc/4.0/
dc.subjectOsmiumeng
dc.subjectHydrido Complexeseng
dc.subjectProton-coupled Electron Transfereng
dc.subjectElectrochemistryeng
dc.subjectDensity Functional Theoryeng
dc.subject.ddc540 Chemie und zugeordnete Wissenschaftennone
dc.titleIsolation of an Osmium(III) Hydrido Complexnone
dc.typearticle
dc.identifier.urnurn:nbn:de:kobv:11-110-18452/29187-8
dc.identifier.doihttp://dx.doi.org/10.18452/28553
dc.type.versionpublishedVersionnone
local.edoc.pages7none
local.edoc.type-nameZeitschriftenartikel
local.edoc.container-typeperiodical
local.edoc.container-type-nameZeitschrift
dc.description.versionPeer Reviewednone
dc.identifier.eissn1521-3749
dcterms.bibliographicCitation.doi10.1002/zaac.202300249
dcterms.bibliographicCitation.journaltitleZeitschrift für anorganische und allgemeine Chemienone
dcterms.bibliographicCitation.volume650none
dcterms.bibliographicCitation.issue5-6none
dcterms.bibliographicCitation.articlenumbere202300249none
dcterms.bibliographicCitation.originalpublishernameWiley-VCHnone
dcterms.bibliographicCitation.originalpublisherplaceWeinheimnone
bua.departmentMathematisch-Naturwissenschaftliche Fakultätnone

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